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Isothermal (vapor plus liquid) equilibria and excess enthalpy data of {1-hexene plus methyl butyl ether (MBE)} and {1-hexene plus methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Identifieur interne : 000824 ( Main/Exploration ); précédent : 000823; suivant : 000825

Isothermal (vapor plus liquid) equilibria and excess enthalpy data of {1-hexene plus methyl butyl ether (MBE)} and {1-hexene plus methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Auteurs : Rachida Hani [Algérie] ; Roland Solimando [France] ; Latifa Negadi [Algérie] ; Jacques Jose [France] ; Ahmed Ait Kaci [Algérie]

Source :

RBID : Hal:hal-00777035

English descriptors

Abstract

The vapor pressures of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary mixtures and of the three pure components were measured by means of a static device at temperatures between (263 and 333) K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions were calculated for several constant temperatures and fitted to a third-order Redlich-Kister equation using the Barker's method. Additionally, molar excess enthalpies, H-E, for the two binary systems have been measured at 303.15 K using an isothermal flow calorimeter.

Url:
DOI: 10.1016/j.jct.2012.03.016


Affiliations:


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Le document en format XML

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<idno type="DOI">10.1016/j.jct.2012.03.016</idno>
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<title level="j">Journal of Chemical Thermodynamics</title>
<idno type="ISSN">0021-9614</idno>
<imprint>
<date type="datePub">2012</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="mix" xml:lang="en">
<term>(Vapor plus liquid) equilibria</term>
<term>1-Hexene</term>
<term>2ND VIRIAL-COEFFICIENTS</term>
<term>313.15 K</term>
<term>CYCLOHEXANE</term>
<term>Ether</term>
<term>Excess Gibbs free energy</term>
<term>Excess enthalpy</term>
<term>HEPTANE</term>
<term>METHANOL</term>
<term>MOLAR ENTHALPIES</term>
<term>ND/OR SUBSTITUTION HYDROCARBONS</term>
<term>PREDICTION</term>
<term>TERNARY MIXTURES</term>
<term>THERMODYNAMICS</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">The vapor pressures of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary mixtures and of the three pure components were measured by means of a static device at temperatures between (263 and 333) K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions were calculated for several constant temperatures and fitted to a third-order Redlich-Kister equation using the Barker's method. Additionally, molar excess enthalpies, H-E, for the two binary systems have been measured at 303.15 K using an isothermal flow calorimeter.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>Algérie</li>
<li>France</li>
</country>
<region>
<li>Auvergne-Rhône-Alpes</li>
<li>Grand Est</li>
<li>Lorraine (région)</li>
<li>Rhône-Alpes</li>
</region>
<settlement>
<li>Lyon</li>
<li>Metz</li>
<li>Nancy</li>
</settlement>
<orgName>
<li>Université Claude Bernard Lyon 1</li>
<li>Université de Lorraine</li>
<li>Université de Lyon</li>
</orgName>
</list>
<tree>
<country name="Algérie">
<noRegion>
<name sortKey="Hani, Rachida" sort="Hani, Rachida" uniqKey="Hani R" first="Rachida" last="Hani">Rachida Hani</name>
</noRegion>
<name sortKey="Kaci, Ahmed Ait" sort="Kaci, Ahmed Ait" uniqKey="Kaci A" first="Ahmed Ait" last="Kaci">Ahmed Ait Kaci</name>
<name sortKey="Negadi, Latifa" sort="Negadi, Latifa" uniqKey="Negadi L" first="Latifa" last="Negadi">Latifa Negadi</name>
</country>
<country name="France">
<region name="Grand Est">
<name sortKey="Solimando, Roland" sort="Solimando, Roland" uniqKey="Solimando R" first="Roland" last="Solimando">Roland Solimando</name>
</region>
<name sortKey="Jose, Jacques" sort="Jose, Jacques" uniqKey="Jose J" first="Jacques" last="Jose">Jacques Jose</name>
</country>
</tree>
</affiliations>
</record>

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